While I can’t get the video to embed here, this link shows the rotating surface of Pluto as seen through the Hubble in 1994.   This is the work of Alan Stern of the Southwest Research Institute and Marc Buie of Lowell Observatory.

from the link:

“Some of the variations across Pluto’s surface may be caused by topographic features such as basins, or fresh impact craters. However, most of the surface features unveiled by Hubble, including the prominent northern polar cap, are likely produced by the complex distribution of frosts that migrate across Pluto’s surface with its orbital and seasonal cycles and chemical byproducts deposited out of Pluto’s nitrogen-methane atmosphere. The picture was taken in blue light when Pluto was at a distance of 3 billion miles from Earth.”